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Manjiao Deng, Shuling Shen, Xuewen Wang, Yejun Zhang Huarui Xu, Ting Zhang*, and Qiangbin Wang*. Controlled synthesis of AgInS2 nanocrystals and their application in organic–inorganic hybrid photodetectors. CrystEngComm, 2013, 15, 6443-6447.

Abstract

      High quality AgInS2nanocrystals(NCs) are synthesized using a simple single-source precursor method, in which the size and morphology of the products can be precisely controlled from heliotrope seed-like NCs of 6 × 12 nm to heliotrope seed-like dimer NCs of 8 × 16 nm by tuning the composition of the coordinatingsolventsofoleic acidand1-dodecanethiol. The results show that1-dodecanethiolplays a dominant role in determining the morphology of AgInS2 NCs due to its strong absorption onto the {001} crystal plane of AgInS2 NCs. The photoelectric properties of the as-prepared AgInS2 NCs have been characterized using AgInS2-poly(3-hexylthiophene) hybrid nanodevices. The results illustrate that the AgInS2 NCs present very high photosensitivity and photostability to outside illumination. The high sensitivity and stability of the hybrid nanodevice indicate a broad spectrum of applications in the photoelectric nanodevices.



Full Article:http://pubs.rsc.org/en/content/articlelanding/2013/ce/c3ce40173a